Metal Injection Molding Powders

metal injection powder

Exploring the Versatility of Metal Injection Molding Powders

Metal Injection Molding (MIM) is a sophisticated process that merges the versatility of plastic injection molding with the mechanical properties and durability of metal. This process relies heavily on the type of MIM powder used, which significantly influences the properties and quality of the final products. This article delves into various MIM powders and their specific alloys, offering insight into their applications and benefits.

 

Metal Injection Molding Powder

MIM powders are finely processed metals designed for injection molding. These powders are typically less than 20 microns in diameter and are combined with a binder to form a feedstock, which is then molded, debinded, and sintered. The characteristics of MIM powders—such as particle size, shape, and distribution—affect the flow during molding and the strength and precision of the final parts.

MIM Powder Alloys

The choice of alloy in MIM technology depends on the required properties of the final component, such as strength, magnetic properties, corrosion resistance, and thermal conductivity. Below, we explore various alloys used in MIM processes:

 

Cobalt Alloys:

These alloys are renowned for their strength at high temperatures and resistance to wear and corrosion, making them suitable for aerospace components and medical implants.

Cobalt Alloys are used in harsh environments where high strength and corrosion resistance are necessary.

Alloy Type Chemical Composition Density (g/cm³) Hardness (HV) Tensile Strength (MPa) Elongation (%) Corrosion Resistance
Co-Cr-Mo Co-Bal, Cr-27-30%, Mo-5-7% 8.3 – 8.6 300 – 450 900 – 1200 8 – 15 Excellent
Co-Ni-Cr Co-Bal, Ni-10-20%, Cr-15-20% 8.4 – 8.7 250 – 400 800 – 1100 10 – 20 Very Good
Co-Cr-W Co-Bal, Cr-20-30%, W-10-15% 8.5 – 9.0 350 – 500 950 – 1300 5 – 10 Excellent

 

Copper Alloys:

Known for excellent thermal and electrical conductivity, copper alloys are ideal for creating heat sinks, electrical connectors, and other components where heat dissipation or electrical conduction is crucial.

Copper Alloys are chosen for their superior conductivity in electronic and electrical applications.

Alloy Type Chemical Composition Density (g/cm³) Hardness (HV) Tensile Strength (MPa) Elongation (%) Conductivity (% IACS)
Cu-C10 Cu-Bal, Be-1-2%, Ni-0.2-0.5% 8.7 – 8.9 100 – 180 500 – 700 20 – 40 15 – 20
Cu-Ni-Sn Cu-Bal, Ni-4-6%, Sn-6-8% 8.4 – 8.6 140 – 220 600 – 800 10 – 25 10 – 15
Cu-Ni-Zn Cu-Bal, Ni-10-20%, Zn-10-15% 8.3 – 8.6 130 – 200 500 – 650 25 – 35 5 – 10
Cu-Zn (Brass) Cu-Bal, Zn-20-30% 8.2 – 8.5 90 – 160 450 – 600 30 – 45 28 – 34
Cu-Sn (Bronze) Cu-Bal, Sn-6-12% 8.8 – 9.0 110 – 150 550 – 750 15 – 30 15 – 20

 

Nickel Alloys:

Often referred to as superalloys, nickel alloys are favored for their exceptional high-temperature strength and corrosion resistance, perfect for gas turbine blades, aerospace components, and energy sector applications.

Nickel Alloys serve well in high-temperature environments where thermal stability and corrosion resistance are critical.

Alloy Type Chemical Composition Density (g/cm³) Hardness (HV) Tensile Strength (MPa) Elongation (%) Corrosion Resistance
Ni-625 Ni-Bal, Cr-20-23%, Mo-8-10%, Nb-3.15-4.15% 8.4 – 8.8 200 – 300 800 – 1200 30 – 50 Excellent
Ni-718 Ni-Bal, Cr-17-21%, Nb-4.75-5.5%, Mo-2.8-3.3% 8.2 – 8.5 250 – 400 900 – 1500 20 – 45 Excellent
Ni-Cr-Fe Ni-Bal, Cr-15-18%, Fe-6-10% 8.1 – 8.4 180 – 240 500 – 750 40 – 55 Very Good
Ni-Cr-Co Ni-Bal, Cr-16-21%, Co-15-21% 8.3 – 8.6 220 – 350 950 – 1400 25 – 40 Excellent
Ni-Cu Ni-Bal, Cu-28-34% 8.7 – 9.0 120 – 180 450 – 700 20 – 35 Excellen

 

 

Titanium Alloys:

These alloys are chosen for their high strength-to-weight ratio, excellent corrosion resistance, and biocompatibility, making them ideal for aerospace, medical, and automotive applications.

Titanium Alloys are beneficial in the medical field for surgical instruments and implants due to their biocompatibility and strength.

Alloy Type Chemical Composition Density (g/cm³) Hardness (HV) Tensile Strength (MPa) Elongation (%) Applications
Ti-6Al-4V Ti-Bal, Al-6%, V-4% 4.43 330 – 380 900 – 1100 10 – 16 Aerospace, Medical
Ti-6Al-7Nb Ti-Bal, Al-6%, Nb-7% 4.50 340 – 390 950 – 1150 8 – 14 Medical Implants
Ti-5Al-2.5Sn Ti-Bal, Al-5%, Sn-2.5% 4.48 300 – 350 850 – 1000 12 – 18 Aerospace, Cryogenic
Ti-CP Pure Titanium (Commercially Pure Grades) 4.51 200 – 240 240 – 550 20 – 40 Chemical, Marine

 


Master Alloys:

These are used to enhance the properties of base metals, improving their castability, durability, and performance in final applications.

Master Alloys help in refining the structure and properties of metallic components.

Master Alloy Composition Typical Use Effects on Base Metal Common Applications
Nickel Boron (NiB) Ni-3-5% B Grain Refiner Enhances hardenability, improves fluidity Stainless Steel, Tool Steels
Copper Phosphorus (CuP) Cu-7-9% P Deoxidizer Improves conductivity, reduces porosity Copper Alloys, Electrical Components
Aluminum Titanium Boron (AlTiB) Al-5% Ti, 1% B Grain Refiner Refines grain, increases strength and ductility Aluminum Alloys, Aerospace Components
Titanium Carbon (TiC) Ti-0.5-2% C Carbide Former Increases wear resistance, hardness Tool Steels, Wear Parts
Ferro Silicon (FeSi) Fe-15-90% Si Deoxidizer, Alloying Enhances electrical properties, reduces melting point Iron Alloys, Automotive Parts

 


Low Alloy Steels:

Often used in automotive and industrial applications, these steels provide high strength and toughness at a lower cost compared to other exotic metals.

Low Alloy Steels are preferred for general engineering and automotive components due to their balanced properties and cost-effectiveness.

Alloy Type Chemical Composition Density (g/cm³) Hardness (HV) Tensile Strength (MPa) Elongation (%) Applications
4140 Fe, 0.8-1.1% C, 0.8-1.1% Cr, 0.15-0.25% Mo 7.7 – 7.9 200 – 350 700 – 1000 10 – 25 Automotive, Aerospace
8620 Fe, 0.18-0.23% C, 0.4-0.7% Ni, 0.4-0.7% Cr, 0.15-0.25% Mo 7.6 – 7.8 150 – 300 500 – 700 20 – 35 Gears, Crankshafts
4605 Fe, 0.2-0.3% C, 1.65-2.0% Ni, 0.4-0.6% Mo 7.7 – 7.9 170 – 280 600 – 850 15 – 30 Bearings, Connectors
4340 Fe, 0.38-0.43% C, 1.65-2.0% Ni, 0.7-0.9% Cr, 0.2-0.3% Mo 7.8 – 7.9 250 – 400 800 – 1200 12 – 28 Aerospace, Automotive
17-4 PH Stainless Steel Fe, 0.07% C, 15-17.5% Cr, 3-5% Ni, 3-5% Cu, 0.15-0.45% Nb 7.75 – 7.85 300 – 450 950 – 1150 8 – 18 Aerospace, Medical

 


 

Soft Magnetic Alloys:

These alloys are essential in electrical and electronic applications, offering necessary magnetic properties for inductors, transformers, and various sensing devices.

Soft Magnetic Alloys are vital in telecommunications and electronic industries.

Alloy Type Chemical Composition Relative Permeability Saturation Magnetization (Tesla) Coercivity (A/m) Electrical Resistivity (μΩ·cm) Common Applications
Fe-Ni (Permalloy) Fe-78% Ni-22% 100,000 – 200,000 1.6 0.8 – 4 50 – 60 Shielding, Transformers
Fe-Si Fe-97%, Si-3% 10,000 – 30,000 2.0 40 – 100 70 – 100 Electric Motors, Generators
Fe-Ni-Mo (Mumetal) Fe-76%, Ni-17%, Mo-5%, Cu-2% 250,000 – 400,000 0.8 0.2 – 1.0 80 – 100 Sensors, Magnetic Shielding
Fe-Co-V (Hiperco) Fe-49%, Co-49%, V-2% 20,000 – 35,000 2.4 8 – 15 25 – 40 Actuators, Relays
Fe-Co-Ni (Fecoflux) Fe-72%, Co-20%, Ni-5%, Mo-3% 15,000 – 25,000 1.9 10 – 20 40 – 50 Magnetic Cores, Rotors

 


Tool Steels and High-speed Steels:

Characterized by their hardness and resistance to abrasion, these steels are used in the production of cutting tools, drills, and other machining components that require high wear resistance.

Tool Steels and High-speed Steels are indispensable in the tooling industry for their durability and performance under stress.

Alloy Type Chemical Composition Hardness (HRC) Tensile Strength (MPa) Impact Toughness (J/cm²) Wear Resistance Applications
M2 High-Speed Steel W-6%, Mo-5%, V-2%, Cr-4%, C-0.85% 60 – 65 2800 – 3400 20 – 25 High Drills, Cutting Tools
T15 High-Speed Steel W-12%, Co-5%, V-4%, Cr-4%, C-1.6% 63 – 67 3000 – 3500 15 – 20 Very High Taps, Milling Cutters
D2 Tool Steel Cr-12%, Mo-1%, V-0.8%, C-1.5% 55 – 62 2500 – 3100 10 – 15 High Punches, Dies
H13 Tool Steel Cr-5%, Mo-1.3%, V-1%, Si-1%, C-0.4% 50 – 55 1700 – 2300 25 – 30 Moderate Forging Dies, Extrusion Dies
A2 Tool Steel Cr-5%, Mo-1%, V-0.3%, C-1% 57 – 62 1900 – 2400 20 – 25 Moderate Stamping Dies, Shear Blades

 




The Spectrum of Stainless Steel MIM Powders: Properties and Applications

Stainless steel MIM powders are crucial for producing parts that combine aesthetic appeal with high mechanical performance and corrosion resistance. These powders are characterized by their fine particle size, typically ranging between 10 and 22 microns, which ensures high packing density and uniform sintering behavior, critical for achieving optimal mechanical properties.

Types of Stainless Steel Used in MIM

Stainless steel can be broadly categorized into five groups based on their microstructure and heat treatment capabilities: duplex, austenitic, ferritic, martensitic, and precipitation hardening stainless steels. Each category offers unique properties for specific applications:

  • Duplex Stainless Steel

    • Properties: Duplex stainless steels combine austenitic and ferritic stainless steel characteristics, offering high strength and excellent resistance to corrosion and stress corrosion cracking.
    • Applications: They are widely used in oil and gas exploration, chemical processing equipment, and marine environments.
Alloy Type Chemical Composition Density (g/cm³) Yield Strength (MPa) Tensile Strength (MPa) Elongation (%) Corrosion Resistance Applications
2205 Fe, 22% Cr, 5.5% Ni, 3% Mo, 0.15% N 7.8 450 – 620 620 – 900 25 – 45 Excellent, especially in chloride environments Oil & Gas, Marine, Pulp & Paper
2507 (Super Duplex) Fe, 25% Cr, 7% Ni, 4% Mo, 0.27% N 7.8 550 – 795 795 – 1020 25 – 40 Exceptional, superior to 2205 in chloride environments Desalination, Subsea Equipment
2304 Fe, 23% Cr, 4% Ni, 0.1% N 7.8 400 – 550 600 – 750 25 – 40 Good, better than 316L in chloride environments Construction, Transport Frames
LDX 2101 Fe, 21.5% Cr, 1.5% Ni, 0.3% Mo, 0.22% N 7.7 450 – 650 650 – 900 30 – 40 Very Good, high resistance to localized corrosion Bridges, Water Treatment Plants
UR2202 Fe, 22% Cr, 2% Ni, 0.3% Mo 7.6 400 – 550 600 – 800 30 – 45 Very Good, enhanced resistance to stress corrosion cracking Chemical Tankers, Architecture

 


 

  • Austenitic Stainless Steel

    • Properties: Known for their non-magnetic behavior and excellent formability, austenitic steels have superior corrosion resistance and maintain their strength at high temperatures.
    • Applications: Commonly used in food processing equipment, kitchen utensils, medical devices, and automotive trim.
Alloy Type Chemical Composition Density (g/cm³) Yield Strength (MPa) Tensile Strength (MPa) Elongation (%) Corrosion Resistance Applications
304 Fe, 18% Cr, 8% Ni 7.9 215 – 250 505 – 720 40 – 60 Very Good Kitchen Equipment, Architecture
316 Fe, 16% Cr, 10% Ni, 2% Mo 8.0 240 – 290 515 – 750 40 – 60 Excellent, especially against chloride corrosion Medical, Marine Applications
310 Fe, 25% Cr, 20% Ni 7.9 205 – 250 520 – 725 40 – 50 Good, high temperature resistance Furnaces, Heat Exchangers
321 Fe, 17% Cr, 9% Ni, 0.3% Ti 7.9 205 – 240 515 – 720 40 – 60 Very Good, similar to 304 but with better stability at high temps Aerospace, Exhaust Systems
904L Fe, 20% Cr, 25% Ni, 4.5% Mo, 1.5% Cu 8.0 220 – 250 490 – 700 35 – 55 Excellent, superior corrosion resistance to 316 Seawater, Chemical Processing

 


  • Ferritic Stainless Steel

    • Properties: Ferritic stainless steels are magnetic, have good corrosion resistance, and better engineering properties than austenitic grades but are less ductile.
    • Applications: They are often employed in automotive parts, industrial equipment, and indoor architecture.
Alloy Type Chemical Composition Density (g/cm³) Yield Strength (MPa) Tensile Strength (MPa) Elongation (%) Corrosion Resistance Applications
430 Fe, 16% Cr 7.7 205 – 310 450 – 600 20 – 25 Good, moderate environments Appliances, Automotive trim
409 Fe, 11% Cr, 0.5% Ti 7.6 170 – 380 380 – 560 20 – 22 Fair, suitable for high temperatures Exhaust systems, Heat exchangers
441 Fe, 18% Cr, 0.5% Ni, 0.5% Ti 7.7 230 – 310 500 – 670 25 – 30 Good, better high temperature and corrosion resistance Automotive exhaust parts
434 Fe, 16-18% Cr, 0.8-2% Mo 7.7 275 – 350 415 – 585 22 – 28 Very Good, increased resistance to corrosion Automotive trim, Fasteners
444 Fe, 18% Cr, 2% Mo, 0.4% Ni 7.7 275 – 380 410 – 580 20 – 25 Excellent, high resistance to chloride corrosion Water heaters, Solar panels

 


  • Martensitic Stainless Steel

    • Properties: Martensitic grades are known for their hardness and high strength achieved through heat treatment; however, they are less resistant to corrosion.
    • Applications: Ideal for cutlery, surgical instruments, and other applications where high strength and moderate corrosion resistance are required.
Alloy Type Chemical Composition Density (g/cm³) Hardness (HRC) Yield Strength (MPa) Tensile Strength (MPa) Elongation (%) Corrosion Resistance Applications
410 Fe, 12% Cr, 0.15% C 7.8 28 – 35 450 – 550 650 – 750 15 – 20 Moderate Cutlery, Nozzles, Fasteners
420 Fe, 13% Cr, 0.15-0.40% C 7.8 45 – 50 600 – 700 650 – 900 12 – 20 Moderate Surgical instruments, Blades
440C Fe, 17% Cr, 1% Mo, 1.1% C 7.8 58 – 60 580 – 680 760 – 1980 12 – 18 Good Bearings, Knives, Precision equipment
431 Fe, 15-17% Cr, 1.25-2.5% Ni, 0.2% C 7.8 25 – 32 600 – 800 800 – 1000 10 – 15 Good Pump shafts, Fittings
17-4 PH Fe, 15-17% Cr, 4% Ni, 3-5% Cu, 0.07% C, Nb + Ta 7.8 33 – 44 1100 – 1300 1000 – 1400 5 – 15 Excellent

  • Precipitation Hardening Stainless Steel

    • Properties: These steels can be hardened and strengthened through heat treatments, providing excellent mechanical strength and good corrosion resistance.
    • Applications: Used in aerospace, chemical, and food processing industries where parts must withstand high stress and corrosive environments.
Alloy Type Chemical Composition Density (g/cm³) Hardness (HRC) Yield Strength (MPa) Tensile Strength (MPa) Elongation (%) Corrosion Resistance Applications
17-4 PH Fe, 15-17% Cr, 4% Ni, 3-5% Cu, 0.07% C, Nb + Ta 7.8 33 – 44 1100 – 1300 1000 – 1400 5 – 15 Excellent Aerospace, Medical Devices
15-5 PH Fe, 14-15.5% Cr, 4.5-5.5% Ni, 3.5% Cu, 0.07% C 7.8 30 – 45 1050 – 1250 950 – 1150 8 – 18 Excellent Aerospace, Marine Components
13-8 Mo Fe, 12.25-13.25% Cr, 7.5-8.5% Ni, 2.0% Mo, 0.01% C 7.8 33 – 43 1100 – 1300 950 – 1200 10 – 15 Very Good Aircraft Components, Fasteners
A-286 Fe, 13.5-16% Cr, 24-27% Ni, 1.9-2.35% Ti, 0.08% C 7.9 24 – 35 900 – 1150 1000 – 1200 12 – 20 Good Jet Engines, Turbine Components
Custom 450 Fe, 14.5-15.5% Cr, 6-7.5% Ni, 1.25-1.75% Mo, 0.05% C 7.8 28 – 38 1000 – 1200 950 – 1150 10 – 20 Excellent Medical Instruments, Springs

Advantages of Stainless Steel MIM

The MIM process offers several advantages when working with stainless steel powders:

  • Complex Geometries: Enables the production of components with complex shapes that would be challenging or impossible to achieve through traditional manufacturing methods.
  • High Precision: Achieves tight tolerances and excellent surface finish, reducing the need for secondary machining.
  • Cost-Effective: Particularly for large production volumes, MIM reduces waste and energy consumption compared to traditional forging and machining.

 

mim powder  mim powder

Stainless steel alloy powder


 

Understanding MIM Powder Manufacturing Methods: Gas vs. Water Atomization

The quality of MIM powders significantly impacts the properties of the final molded parts, such as density, strength, and surface finish. The choice of atomization method is crucial in determining the shape, size distribution, and purity of the metal powders.

 

Gas Atomized Powder

    • Process Description: In gas atomization, molten metal is exposed to a high-velocity jet of inert gas, typically argon or nitrogen, which disperses the liquid metal into fine droplets that solidify as they cool while suspended in the gas stream. This method produces powders with a spherical shape, which is ideal for MIM due to the excellent flow characteristics required for the injection molding process.
    • Advantages: Gas atomized powders are characterized by their very low oxygen content and high purity. The spherical particles ensure uniform packing and consistent sintering, leading to high-density and mechanically robust final products.
    • Applications: Due to their superior quality, gas atomized powders are preferred in aerospace, automotive, and medical industries where high performance and precision are critical.

 

Water Atomized Powder

    • Process Description: Water atomization involves hitting a stream of molten metal with high-pressure jets of water. This method cools the metal rapidly, breaking it into particles that are generally more irregular in shape compared to gas atomized powders. The rapid cooling often leads to higher levels of oxygen and other impurities within the powder.
    • Advantages: Water atomization is more cost-effective than gas atomization. The process is energy-efficient and can be scaled up to produce large quantities of powder, making it suitable for less critical applications.
    • Applications: Water atomized powders are commonly used in automotive components, construction hardware, and general industrial applications where the ultimate performance criteria are less demanding.

Difference between Water and Gas Atomized Powder

While both gas and water atomization are effective for producing metal powders for MIM, they differ significantly in several key aspects:

  • Particle Shape and Size: Gas atomized powders tend to have a more uniform and spherical shape, facilitating better flow and packing density in the mold. Water atomized powders, however, are typically more irregular and coarse, which can affect the consistency and quality of the final product.
  • Purity and Oxygen Content: Gas atomization typically results in powders with lower oxygen content due to the inert atmosphere in which the particles solidify. This is crucial for applications requiring high mechanical properties and thermal stability. Water atomization, while efficient, generally leads to higher oxygen content due to the oxidation that occurs when molten metal interacts with water.
  • Cost and Scalability: Water atomization is less expensive and more scalable due to the lower cost of water compared to inert gases and the simpler setup. Gas atomization, though more costly, is essential for producing high-grade powders needed in high-specification applications.

 


 

Optimizing MIM Powder Choice: Particle Size and Shape Considerations

MIM Powder Choice

Selecting the right MIM powder involves a deep understanding of the material’s properties and how they affect the molding process and the final part. The decision hinges on various factors including the type of metal, its purity, particle size, shape, and cost. These factors influence the flowability of the powder, density of the molded part, and its mechanical properties post-sintering.

Particle Size and Particle Size Distribution (PSD)

Particle size and its distribution are fundamental properties that affect the performance of the MIM process in several ways:

  • Flowability: Smaller particles can reduce flowability but increase the green strength of the molded part, whereas larger particles improve flow but may reduce the strength. A well-controlled PSD ensures that the powder can be easily and consistently injected into molds.
  • Packing Density: Optimal particle size helps achieve higher packing density, which is crucial for reducing porosity in the final product. A higher packing density leads to better mechanical properties and surface finish.
  • Sintering Behavior: Uniform particle size distribution aids in uniform sintering, reducing defects such as distortion or warping of the component. The particle size also affects the sintering temperature and time, impacting the production efficiency.

Manufacturers typically aim for a PSD that balances these factors to suit the specific requirements of the product being molded. Commonly, a PSD with a median particle size (D50) ranging from 10 to 22 microns is preferred in MIM processes.

 

Particle Shape

The shape of MIM powder particles plays a significant role in the molding and sintering processes:

  • Spherical Particles: These are ideal for MIM as they have excellent flow properties, allowing the powder to fill mold cavities more effectively. Spherical particles also pack more densely, leading to higher mechanical strength and a smoother surface finish on the final product.
  • Irregular Particles: While less expensive to produce, irregular particles can lead to issues with flowability and packing density. They are more prone to interlocking, which can cause variability in the injection molding process and result in defects in the sintered parts.

mim powder

 

Great!  JHMIM engineering team’s expertise in selecting the right MIM powder and their ability to optimize the process based on specific requirements is a strong asset. This strategic approach allows them to effectively balance property needs with cost considerations, ensuring optimal outcomes for their projects. If there’s anything more specific you’d like to explore about MIM technology or another topic, feel free to ask!

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